Abstract
The migrations of different groups to the metal-carbene center of Rh II-stabilized iminocarbenes that were derived from N-sulfonyl triazoles are discussed (see scheme). The reactivity of these Rh-iminocabenes can be tuned easily by variation of substituents on the parent triazole.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1371-1373 |
| Number of pages | 3 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 52 |
| Issue number | 5 |
| DOIs | |
| State | Published - Jan 28 2013 |
| Externally published | Yes |
Keywords
- carbenes
- enamines
- migration
- rhodium
- triazoles
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)