The development and scope of a versatile tandem Stille-oxa-electrocyclization reaction

Uttam K. Tambar; Taichi Kano; John F. Zepernick; Brian M. Stoltz

doi:10.1016/j.tetlet.2006.11.097

The development and scope of a versatile tandem Stille-oxa-electrocyclization reaction

Uttam K. Tambar, Taichi Kano, John F. Zepernick, Brian M. Stoltz

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

A palladium-catalyzed tandem Stille-oxa-electrocyclization reaction has been developed for the convergent preparation of highly substituted polycyclic pyran systems. The strategy presented in this letter is an alternative to the known methods for constructing similar pyran systems. The substrate scope of this diastereoselective transformation is explored.

Original language	English (US)
Pages (from-to)	345-350
Number of pages	6
Journal	Tetrahedron Letters
Volume	48
Issue number	3
DOIs	https://doi.org/10.1016/j.tetlet.2006.11.097
State	Published - Jan 15 2007

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2006.11.097

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abstract = "A palladium-catalyzed tandem Stille-oxa-electrocyclization reaction has been developed for the convergent preparation of highly substituted polycyclic pyran systems. The strategy presented in this letter is an alternative to the known methods for constructing similar pyran systems. The substrate scope of this diastereoselective transformation is explored.",

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AU - Zepernick, John F.

AU - Stoltz, Brian M.

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AB - A palladium-catalyzed tandem Stille-oxa-electrocyclization reaction has been developed for the convergent preparation of highly substituted polycyclic pyran systems. The strategy presented in this letter is an alternative to the known methods for constructing similar pyran systems. The substrate scope of this diastereoselective transformation is explored.

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The development and scope of a versatile tandem Stille-oxa-electrocyclization reaction

Abstract

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