Stereochemical assignment in acyclic lipids across long distance by circular dichroism: Absolute stereochemistry of the aglycone of caminoside A

John B. MacMillan; Roger G. Linington; Raymond J. Andersen; Tadeusz F. Molinski

doi:10.1002/anie.200461158

Stereochemical assignment in acyclic lipids across long distance by circular dichroism: Absolute stereochemistry of the aglycone of caminoside A

John B. MacMillan, Roger G. Linington, Raymond J. Andersen, Tadeusz F. Molinski

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Information technology: The configuration at C10-OH of the caminoside aglycone (see formula) was shown to be R by interpretation of exciton coupling in the circular dichroism (CD) spectrum of the tetraphenylporphyrin carboxylate diester of (2R,10R)-2,10-nonadecanediol. This compound is derived from the title compound and was embedded in highly uniform nanometric liposomes for the CD measurements.

Original language	English (US)
Pages (from-to)	5946-5951
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	44
DOIs	https://doi.org/10.1002/anie.200461158
State	Published - Nov 12 2004

Keywords

Circular dichroism
Glycolipids
Liposomes
Natural products
Stereochemistry

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200461158

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Stereochemical assignment in acyclic lipids across long distance by circular dichroism: Absolute stereochemistry of the aglycone of caminoside A. / MacMillan, John B.; Linington, Roger G.; Andersen, Raymond J. et al.
In: Angewandte Chemie - International Edition, Vol. 43, No. 44, 12.11.2004, p. 5946-5951.

Research output: Contribution to journal › Article › peer-review

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Stereochemical assignment in acyclic lipids across long distance by circular dichroism: Absolute stereochemistry of the aglycone of caminoside A

Abstract

Keywords

ASJC Scopus subject areas

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