Solid-State 31P CP-MAS NMR Study of Phosphine Complexes of Mercury(II)

Tim Allman; R. E. Lenkinski

doi:10.1021/ic00238a022

Solid-State ³¹P CP-MAS NMR Study of Phosphine Complexes of Mercury(II)

Tim Allman, R. E. Lenkinski

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27 Scopus citations

Abstract

The solid-state ³¹P CP-MAS NMR spectra of several phosphine complexes of mercury(II) with known crystal structures have been measured. In addition, some simple valence bond calculations were performed and an attempt was made to relate calculated s characters of bonding orbitals to the measured Hg-P coupling constants. The correlation predicted by an approximation to the Fermi contact term was not found.

Original language	English (US)
Pages (from-to)	3202-3204
Number of pages	3
Journal	Inorganic Chemistry
Volume	25
Issue number	18
DOIs	https://doi.org/10.1021/ic00238a022
State	Published - Aug 1986

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic00238a022

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title = "Solid-State 31P CP-MAS NMR Study of Phosphine Complexes of Mercury(II)",

abstract = "The solid-state 31P CP-MAS NMR spectra of several phosphine complexes of mercury(II) with known crystal structures have been measured. In addition, some simple valence bond calculations were performed and an attempt was made to relate calculated s characters of bonding orbitals to the measured Hg-P coupling constants. The correlation predicted by an approximation to the Fermi contact term was not found.",

author = "Tim Allman and Lenkinski, {R. E.}",

year = "1986",

month = aug,

doi = "10.1021/ic00238a022",

language = "English (US)",

volume = "25",

pages = "3202--3204",

journal = "Inorganic Chemistry",

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publisher = "American Chemical Society",

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T1 - Solid-State 31P CP-MAS NMR Study of Phosphine Complexes of Mercury(II)

AU - Allman, Tim

AU - Lenkinski, R. E.

PY - 1986/8

Y1 - 1986/8

N2 - The solid-state 31P CP-MAS NMR spectra of several phosphine complexes of mercury(II) with known crystal structures have been measured. In addition, some simple valence bond calculations were performed and an attempt was made to relate calculated s characters of bonding orbitals to the measured Hg-P coupling constants. The correlation predicted by an approximation to the Fermi contact term was not found.

AB - The solid-state 31P CP-MAS NMR spectra of several phosphine complexes of mercury(II) with known crystal structures have been measured. In addition, some simple valence bond calculations were performed and an attempt was made to relate calculated s characters of bonding orbitals to the measured Hg-P coupling constants. The correlation predicted by an approximation to the Fermi contact term was not found.

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U2 - 10.1021/ic00238a022

DO - 10.1021/ic00238a022

M3 - Article

AN - SCOPUS:0000821591

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 18

ER -

Solid-State ³¹P CP-MAS NMR Study of Phosphine Complexes of Mercury(II)

Abstract

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