Removal of Sulfur Groups from Molecules by Copper(I). Preparation of Sulfur-Substituted 1,3-Dienes for the Diels-Alder Reaction

Theodore Cohen; Albert J. Mura; David W. Shull; Elaine R. Fogel; Robert J. Ruffner; J R Falck

doi:10.1021/jo00881a041

Removal of Sulfur Groups from Molecules by Copper(I). Preparation of Sulfur-Substituted 1,3-Dienes for the Diels-Alder Reaction

Theodore Cohen, Albert J. Mura, David W. Shull, Elaine R. Fogel, Robert J. Ruffner, J R Falck

Biochemistry

Research output: Contribution to journal › Letter › peer-review

94 Scopus citations

Abstract

The elimination of thiophenol by copper(I) from readily prepared precursors leads in good yield to several useful phenylthio-subtituted Diels-Alder dienes including (Z)-1-phenylthio-2-methoxy-1,3-butadiene which yields a m-methoxy adduct with methyl vinyl ketone.

Original language	English (US)
Pages (from-to)	3218-3219
Number of pages	2
Journal	Journal of Organic Chemistry
Volume	41
Issue number	19
DOIs	https://doi.org/10.1021/jo00881a041
State	Published - Sep 1 1976

ASJC Scopus subject areas

Organic Chemistry

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title = "Removal of Sulfur Groups from Molecules by Copper(I). Preparation of Sulfur-Substituted 1,3-Dienes for the Diels-Alder Reaction",

abstract = "The elimination of thiophenol by copper(I) from readily prepared precursors leads in good yield to several useful phenylthio-subtituted Diels-Alder dienes including (Z)-1-phenylthio-2-methoxy-1,3-butadiene which yields a m-methoxy adduct with methyl vinyl ketone.",

author = "Theodore Cohen and Mura, {Albert J.} and Shull, {David W.} and Fogel, {Elaine R.} and Ruffner, {Robert J.} and Falck, {J R}",

year = "1976",

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doi = "10.1021/jo00881a041",

language = "English (US)",

volume = "41",

pages = "3218--3219",

journal = "Journal of Organic Chemistry",

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T1 - Removal of Sulfur Groups from Molecules by Copper(I). Preparation of Sulfur-Substituted 1,3-Dienes for the Diels-Alder Reaction

AU - Cohen, Theodore

AU - Mura, Albert J.

AU - Shull, David W.

AU - Fogel, Elaine R.

AU - Ruffner, Robert J.

AU - Falck, J R

PY - 1976/9/1

Y1 - 1976/9/1

N2 - The elimination of thiophenol by copper(I) from readily prepared precursors leads in good yield to several useful phenylthio-subtituted Diels-Alder dienes including (Z)-1-phenylthio-2-methoxy-1,3-butadiene which yields a m-methoxy adduct with methyl vinyl ketone.

AB - The elimination of thiophenol by copper(I) from readily prepared precursors leads in good yield to several useful phenylthio-subtituted Diels-Alder dienes including (Z)-1-phenylthio-2-methoxy-1,3-butadiene which yields a m-methoxy adduct with methyl vinyl ketone.

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DO - 10.1021/jo00881a041

M3 - Letter

AN - SCOPUS:0000948995

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 19

ER -

Removal of Sulfur Groups from Molecules by Copper(I). Preparation of Sulfur-Substituted 1,3-Dienes for the Diels-Alder Reaction

Abstract

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