Abstract
The combination of CrCl2 and silyl chlorides converts aryl and conjugated aldehydes into olefinic adducts in good to excellent yields. When constrained by structural features, the intermediate vic-diol can be isolated. Available data are consistent with a novel chromium Brook rearrangement.
Original language | English (US) |
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Pages (from-to) | 2949-2951 |
Number of pages | 3 |
Journal | Organic Letters |
Volume | 8 |
Issue number | 14 |
DOIs | |
State | Published - Jul 6 2006 |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry