Optically active allenes from an allylic substitution/isomerization sequence

Wenhan Zhang; Joseph M. Ready

doi:10.1002/cctc.201300663

Optically active allenes from an allylic substitution/isomerization sequence

Wenhan Zhang, Joseph M. Ready

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

It takes two to trisubstitute: A two-step procedure involving enantioselective allylic alkylation followed by 1,3 hydrogen shift enables the catalytic asymmetric synthesis of trisubstituted allenes.

Original language	English (US)
Pages (from-to)	3497-3498
Number of pages	2
Journal	ChemCatChem
Volume	5
Issue number	12
DOIs	https://doi.org/10.1002/cctc.201300663
State	Published - Dec 1 2013

Keywords

N-heterocyclic carbenes
asymmetric catalyst
chiral allene
copper
enantioselective allylic substitution

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1002/cctc.201300663

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title = "Optically active allenes from an allylic substitution/isomerization sequence",

abstract = "It takes two to trisubstitute: A two-step procedure involving enantioselective allylic alkylation followed by 1,3 hydrogen shift enables the catalytic asymmetric synthesis of trisubstituted allenes.",

keywords = "N-heterocyclic carbenes, asymmetric catalyst, chiral allene, copper, enantioselective allylic substitution",

author = "Wenhan Zhang and Ready, {Joseph M.}",

year = "2013",

month = dec,

day = "1",

doi = "10.1002/cctc.201300663",

language = "English (US)",

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journal = "ChemCatChem",

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T1 - Optically active allenes from an allylic substitution/isomerization sequence

AU - Zhang, Wenhan

AU - Ready, Joseph M.

PY - 2013/12/1

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N2 - It takes two to trisubstitute: A two-step procedure involving enantioselective allylic alkylation followed by 1,3 hydrogen shift enables the catalytic asymmetric synthesis of trisubstituted allenes.

AB - It takes two to trisubstitute: A two-step procedure involving enantioselective allylic alkylation followed by 1,3 hydrogen shift enables the catalytic asymmetric synthesis of trisubstituted allenes.

KW - N-heterocyclic carbenes

KW - asymmetric catalyst

KW - chiral allene

KW - copper

KW - enantioselective allylic substitution

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M3 - Article

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EP - 3498

JO - ChemCatChem

JF - ChemCatChem

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ER -

Optically active allenes from an allylic substitution/isomerization sequence

Abstract

Keywords

ASJC Scopus subject areas

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