TY - JOUR
T1 - Long-range stereo-relay
T2 - Relative and absolute configuration of 1,n-glycols from circular dichroism of liposomal porphyrin esters
AU - MacMillan, John B.
AU - Molinski, Tadeusz F.
N1 - Copyright:
Copyright 2010 Elsevier B.V., All rights reserved.
PY - 2004/8/18
Y1 - 2004/8/18
N2 - The relative and absolute configurations of long-chain syn- and anti-1,5-, 1,7- and 1,9-glycols were determined from exciton-coupled circular dichroism (ECCD) of the corresponding bis-5-(4′-carboxyl)-5,10,15,20-tetraphenylporphyrin esters measured in uniform (φ = 26 nm), unilamellar liposomes. Long-range transmission of configuration by ECCD is made possible through partial ordering of glycol ester-lipid molecules by liposomal bilayers.
AB - The relative and absolute configurations of long-chain syn- and anti-1,5-, 1,7- and 1,9-glycols were determined from exciton-coupled circular dichroism (ECCD) of the corresponding bis-5-(4′-carboxyl)-5,10,15,20-tetraphenylporphyrin esters measured in uniform (φ = 26 nm), unilamellar liposomes. Long-range transmission of configuration by ECCD is made possible through partial ordering of glycol ester-lipid molecules by liposomal bilayers.
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U2 - 10.1021/ja047741a
DO - 10.1021/ja047741a
M3 - Article
C2 - 15303868
AN - SCOPUS:4043077679
SN - 0002-7863
VL - 126
SP - 9944
EP - 9945
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 32
ER -