Homoallyl alcohol as an allylation reagent for termination of the Catellani-Lautens reaction via retro-allylation

Xueyan Du; Xiaozhe Yang; Han Wang; Xinguang Li; Murong Wang; Xiang Li; Ye Tao; Yaxing Yang; Xinqiang Tan; Feng Ren; Ping Xin Zhou; Yong Min Liang

doi:10.1039/d2qo01609e

Homoallyl alcohol as an allylation reagent for termination of the Catellani-Lautens reaction via retro-allylation

Xueyan Du, Xiaozhe Yang, Han Wang, Xinguang Li, Murong Wang, Xiang Li, Ye Tao, Yaxing Yang, Xinqiang Tan, Feng Ren, Ping Xin Zhou, Yong Min Liang

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A palladium/norbornene-catalyzed ortho-amination/allylation of aryl iodides was developed for the construction of ortho-aminated allylbenzene by using N-benzoyloxyamine as the amination reagent and homoallyl alcohol as the allylation reagent. The reaction showed good functional group tolerance and broad substrate scope.

Original language	English (US)
Pages (from-to)	898-904
Number of pages	7
Journal	Organic Chemistry Frontiers
Volume	10
Issue number	4
DOIs	https://doi.org/10.1039/d2qo01609e
State	Published - Dec 22 2022
Externally published	Yes

ASJC Scopus subject areas

Organic Chemistry

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title = "Homoallyl alcohol as an allylation reagent for termination of the Catellani-Lautens reaction via retro-allylation",

abstract = "A palladium/norbornene-catalyzed ortho-amination/allylation of aryl iodides was developed for the construction of ortho-aminated allylbenzene by using N-benzoyloxyamine as the amination reagent and homoallyl alcohol as the allylation reagent. The reaction showed good functional group tolerance and broad substrate scope.",

author = "Xueyan Du and Xiaozhe Yang and Han Wang and Xinguang Li and Murong Wang and Xiang Li and Ye Tao and Yaxing Yang and Xinqiang Tan and Feng Ren and Zhou, {Ping Xin} and Liang, {Yong Min}",

note = "Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",

year = "2022",

month = dec,

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doi = "10.1039/d2qo01609e",

language = "English (US)",

volume = "10",

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journal = "Organic Chemistry Frontiers",

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TY - JOUR

T1 - Homoallyl alcohol as an allylation reagent for termination of the Catellani-Lautens reaction via retro-allylation

AU - Du, Xueyan

AU - Yang, Xiaozhe

AU - Wang, Han

AU - Li, Xinguang

AU - Wang, Murong

AU - Li, Xiang

AU - Tao, Ye

AU - Yang, Yaxing

AU - Tan, Xinqiang

AU - Ren, Feng

AU - Zhou, Ping Xin

AU - Liang, Yong Min

PY - 2022/12/22

Y1 - 2022/12/22

N2 - A palladium/norbornene-catalyzed ortho-amination/allylation of aryl iodides was developed for the construction of ortho-aminated allylbenzene by using N-benzoyloxyamine as the amination reagent and homoallyl alcohol as the allylation reagent. The reaction showed good functional group tolerance and broad substrate scope.

AB - A palladium/norbornene-catalyzed ortho-amination/allylation of aryl iodides was developed for the construction of ortho-aminated allylbenzene by using N-benzoyloxyamine as the amination reagent and homoallyl alcohol as the allylation reagent. The reaction showed good functional group tolerance and broad substrate scope.

UR - http://www.scopus.com/inward/record.url?scp=85146167608&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85146167608&partnerID=8YFLogxK

U2 - 10.1039/d2qo01609e

DO - 10.1039/d2qo01609e

M3 - Article

AN - SCOPUS:85146167608

SN - 2052-4110

VL - 10

SP - 898

EP - 904

JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 4

ER -

Homoallyl alcohol as an allylation reagent for termination of the Catellani-Lautens reaction via retro-allylation

Abstract

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