@article{2617a30628864a3281733a1cbc81ddd9,
title = "Cycloadditions of Donor–Acceptor Cyclopropanes and -butanes using S=N-Containing Reagents: Access to Cyclic Sulfinamides, Sulfonamides, and Sulfinamidines",
abstract = "We present (3+2)- and (4+2)-cycloadditions of donor–acceptor (D–A) cyclopropanes and cyclobutanes with N-sulfinylamines and a sulfur diimide, along with a one-pot, two-step strategy for the formal insertion of HNSO2 into D–A cyclopropanes. These are rare examples of cycloadditions with D–A cyclopropanes and cyclobutanes whereby the 2π component consists of two different heteroatoms, thus leading to five- and six-membered rings containing adjacent heteroatoms.",
keywords = "cycloadditions, cyclopropanes, donor–acceptor systems, sulfinylamines, sulfur diimide",
author = "Oliver, {Gwyndaf A.} and Loch, {Maximilian N.} and Augustin, {Andr{\'e} U.} and Pit Steinbach and Mohammed Sharique and Tambar, {Uttam K.} and Jones, {Peter G.} and Christoph Bannwarth and Werz, {Daniel B.}",
note = "Funding Information: This research was supported by the European Research Council (ERC Consolidator Grant “GAINBYSTRAIN” to D.B.W). C.B. acknowledges funding by the Federal Ministry of Education and Research (BMBF) and the Ministry of Culture and Science of the German State of North Rhine‐Westphalia (MKW) under the Excellence Strategy of the Federal Government and the L{\"a}nder. Simulations were performed with computing resources granted by RWTH Aachen University under project rwth0749. Open Access funding enabled and organized by Projekt DEAL. Funding Information: This research was supported by the European Research Council (ERC Consolidator Grant “GAINBYSTRAIN” to D.B.W). C.B. acknowledges funding by the Federal Ministry of Education and Research (BMBF) and the Ministry of Culture and Science of the German State of North Rhine-Westphalia (MKW) under the Excellence Strategy of the Federal Government and the L{\"a}nder. Simulations were performed with computing resources granted by RWTH Aachen University under project rwth0749. Open Access funding enabled and organized by Projekt DEAL. Publisher Copyright: {\textcopyright} 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH",
year = "2021",
month = dec,
day = "1",
doi = "10.1002/anie.202106596",
language = "English (US)",
volume = "60",
pages = "25825--25831",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "49",
}