Abstract
(2-Tetrahydrofuryl)-silanes and -germanes were obtained in high yield by the heterogeneous liquid-phase hydrogenation of [2-(4,5-dihydrofuryl)]trimethylsilane (I), bis[2-(4,5-dihydrofuryl)]dimethylsilane (II) and [2-(4,5-dihydrofuryl)]trimethylgermane with a Pd/Al2O3 catalyst. The dihydrofurylsilanes I and II were found to undergo disproportionation and dehydrogenation, the latter being involved in both intra- and inter-molecular disproportionation.
Original language | English (US) |
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Pages (from-to) | 163-171 |
Number of pages | 9 |
Journal | Journal of Organometallic Chemistry |
Volume | 294 |
Issue number | 2 |
DOIs | |
State | Published - Oct 15 1985 |
Externally published | Yes |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
- Materials Chemistry