(Chemical Equation Presented) Herein, we propose a modular and general strategy to construct orcinol-type depsides based on the photolysis of functionalized benzodioxinones (I). Notably, resorcinylic esters are obtained without competing isocoumarin (II) formation, exemplified by the first total synthesis of gustastatin in 10 steps from commercially available trihydroxybenzoic acid.
|Original language||English (US)|
|Number of pages||4|
|State||Published - Feb 17 2005|
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry