α-chlorovinylation: Synthesis of 2-chloropropenyl and propargyl alcohols

J R Falck; D. K. Barma; Charles Mioskowski; Thierry Schlama

doi:10.1016/S0040-4039(99)00153-7

α-chlorovinylation: Synthesis of 2-chloropropenyl and propargyl alcohols

J R Falck, D. K. Barma, Charles Mioskowski, Thierry Schlama

Biochemistry

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Formal α-chlorovinylation of aldehydes using CH₃CCl₃/CrCl₂ affords 2-chloropropenyl alcohols from which terminal propargyl alcohols are obtained via base induced elimination.

Original language	English (US)
Pages (from-to)	2091-2094
Number of pages	4
Journal	Tetrahedron Letters
Volume	40
Issue number	11
DOIs	https://doi.org/10.1016/S0040-4039(99)00153-7
State	Published - Mar 12 1999

Keywords

Alcohols
Alkenyl halides
Alkynes
Chromium

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/S0040-4039(99)00153-7

Cite this

@article{c553d5071c974d0d9d354907be6088fc,

title = "α-chlorovinylation: Synthesis of 2-chloropropenyl and propargyl alcohols",

abstract = "Formal α-chlorovinylation of aldehydes using CH3CCl3/CrCl2 affords 2-chloropropenyl alcohols from which terminal propargyl alcohols are obtained via base induced elimination.",

keywords = "Alcohols, Alkenyl halides, Alkynes, Chromium",

author = "Falck, {J R} and Barma, {D. K.} and Charles Mioskowski and Thierry Schlama",

year = "1999",

month = mar,

day = "12",

doi = "10.1016/S0040-4039(99)00153-7",

language = "English (US)",

volume = "40",

pages = "2091--2094",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "11",

}

TY - JOUR

T1 - α-chlorovinylation

T2 - Synthesis of 2-chloropropenyl and propargyl alcohols

AU - Falck, J R

AU - Barma, D. K.

AU - Mioskowski, Charles

AU - Schlama, Thierry

PY - 1999/3/12

Y1 - 1999/3/12

N2 - Formal α-chlorovinylation of aldehydes using CH3CCl3/CrCl2 affords 2-chloropropenyl alcohols from which terminal propargyl alcohols are obtained via base induced elimination.

AB - Formal α-chlorovinylation of aldehydes using CH3CCl3/CrCl2 affords 2-chloropropenyl alcohols from which terminal propargyl alcohols are obtained via base induced elimination.

KW - Alcohols

KW - Alkenyl halides

KW - Alkynes

KW - Chromium

UR - http://www.scopus.com/inward/record.url?scp=0033548670&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0033548670&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(99)00153-7

DO - 10.1016/S0040-4039(99)00153-7

M3 - Article

AN - SCOPUS:0033548670

SN - 0040-4039

VL - 40

SP - 2091

EP - 2094

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 11

ER -

α-chlorovinylation: Synthesis of 2-chloropropenyl and propargyl alcohols

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this