Abstract
Transition metal catalyzed denitrogenative transannulation of a triazole ring has recently received considerable attention as a new concept for the construction of diverse nitrogen-containing heterocyclic cores. This method allows a single-step synthesis of complex nitrogen heterocycles from easily available and cheap triazole precursors. In this Minireview, recent progress of the transition metal catalyzed denitrogenative transannulation of a triazole ring, which was discovered in 2007, is discussed. One two three: Transition-metal catalyzed denitrogenative transannulation of 1,2,3-triazole rings has recently received increasing attention as a new concept for the construction of diverse nitrogen-containing heterocyclic cores in a single step (see scheme).
Original language | English (US) |
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Pages (from-to) | 862-872 |
Number of pages | 11 |
Journal | Angewandte Chemie - International Edition |
Volume | 51 |
Issue number | 4 |
DOIs | |
State | Published - Jan 23 2012 |
Externally published | Yes |
Keywords
- cyclization
- nitrogen heterocycles
- synthetic methods
- transannulation
- transition metals
ASJC Scopus subject areas
- Catalysis
- General Chemistry