TY - JOUR
T1 - The Phase boundary potentials at the interface between two immiscible electrolyte solutions
AU - Markin, V. S.
AU - Volkov, A. G.
PY - 1988/12/31
Y1 - 1988/12/31
N2 - The theoretical aspects of the calculation and measurement of the interphase [phase boundary] potential difference at the interface between two immiscible liquids are examined and the non-thermodynamic tetraphenylborate hypothesis, which makes it possible to determine the standard ion distribution potentials, is discussed. The electrochemical properties of charged interfaces are analysed and equations are presented for the interphase potential jumps in the presence of Donnan equilibrium, incomplete dissociation of the salt, two electrolytes with a common ion, complex formation in one of the phases, and an oxidation-reduction equilibrium. The experimental methods for the measurement of the interphase potential difference and for testing the thermodynamic theory of distribution potentials at reversible interfaces are examined. The bibliography includes 93 references.
AB - The theoretical aspects of the calculation and measurement of the interphase [phase boundary] potential difference at the interface between two immiscible liquids are examined and the non-thermodynamic tetraphenylborate hypothesis, which makes it possible to determine the standard ion distribution potentials, is discussed. The electrochemical properties of charged interfaces are analysed and equations are presented for the interphase potential jumps in the presence of Donnan equilibrium, incomplete dissociation of the salt, two electrolytes with a common ion, complex formation in one of the phases, and an oxidation-reduction equilibrium. The experimental methods for the measurement of the interphase potential difference and for testing the thermodynamic theory of distribution potentials at reversible interfaces are examined. The bibliography includes 93 references.
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U2 - 10.1070/RC1988v057n12ABEH003416
DO - 10.1070/RC1988v057n12ABEH003416
M3 - Article
AN - SCOPUS:84956102500
SN - 0036-021X
VL - 57
SP - 1124
EP - 1141
JO - Russian Chemical Reviews
JF - Russian Chemical Reviews
IS - 12
ER -