Rhodium(I)-catalyzed N–CN bond cleavage: Intramolecular β-cyanation of styrenes

Rui Wang; J R Falck

doi:10.1039/c3cc43597k

Rhodium(I)-catalyzed N–CN bond cleavage: Intramolecular β-cyanation of styrenes

Rui Wang, J R Falck

Biochemistry

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

We report herein the first example of intramolecular cyanation of a styrene by a rhodium(I)-catalyzed N–CN cleavage reaction. Substituents on the arenes or the styrene alpha-position are tolerated. Our results demonstrate that alkene cyanation can indeed be atom economical.

Original language	English (US)
Pages (from-to)	6516-6518
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	58
DOIs	https://doi.org/10.1039/c3cc43597k
State	Published - Jun 25 2013

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Rhodium(I)-catalyzed N–CN bond cleavage: Intramolecular β-cyanation of styrenes",

abstract = "We report herein the first example of intramolecular cyanation of a styrene by a rhodium(I)-catalyzed N–CN cleavage reaction. Substituents on the arenes or the styrene alpha-position are tolerated. Our results demonstrate that alkene cyanation can indeed be atom economical.",

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AU - Falck, J R

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Y1 - 2013/6/25

N2 - We report herein the first example of intramolecular cyanation of a styrene by a rhodium(I)-catalyzed N–CN cleavage reaction. Substituents on the arenes or the styrene alpha-position are tolerated. Our results demonstrate that alkene cyanation can indeed be atom economical.

AB - We report herein the first example of intramolecular cyanation of a styrene by a rhodium(I)-catalyzed N–CN cleavage reaction. Substituents on the arenes or the styrene alpha-position are tolerated. Our results demonstrate that alkene cyanation can indeed be atom economical.

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Rhodium(I)-catalyzed N–CN bond cleavage: Intramolecular β-cyanation of styrenes

Abstract

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