Rhodium-catalyzed transannulation of 1,2,3-triazoles with nitriles

Tony Horneff; Stepan Chuprakov; Natalia Chernyak; Vladimir Gevorgyan; Valery V. Fokin

doi:10.1021/ja805079v

Rhodium-catalyzed transannulation of 1,2,3-triazoles with nitriles

Tony Horneff, Stepan Chuprakov, Natalia Chernyak, Vladimir Gevorgyan, Valery V. Fokin

Research output: Contribution to journal › Article › peer-review

447 Scopus citations

Abstract

Stable and readily available 1-sulfonyl triazoles are converted to the corresponding imidazoles in good to excellent yields via a rhodium(II)-catalyzed reaction with nitriles. Rhodium iminocarbenoids are proposed intermediates.

Original language	English (US)
Pages (from-to)	14972-14974
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	130
Issue number	45
DOIs	https://doi.org/10.1021/ja805079v
State	Published - Nov 12 2008
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja805079v

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title = "Rhodium-catalyzed transannulation of 1,2,3-triazoles with nitriles",

abstract = "Stable and readily available 1-sulfonyl triazoles are converted to the corresponding imidazoles in good to excellent yields via a rhodium(II)-catalyzed reaction with nitriles. Rhodium iminocarbenoids are proposed intermediates.",

author = "Tony Horneff and Stepan Chuprakov and Natalia Chernyak and Vladimir Gevorgyan and Fokin, {Valery V.}",

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doi = "10.1021/ja805079v",

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journal = "Journal of the American Chemical Society",

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T1 - Rhodium-catalyzed transannulation of 1,2,3-triazoles with nitriles

AU - Horneff, Tony

AU - Chuprakov, Stepan

AU - Chernyak, Natalia

AU - Gevorgyan, Vladimir

AU - Fokin, Valery V.

PY - 2008/11/12

Y1 - 2008/11/12

N2 - Stable and readily available 1-sulfonyl triazoles are converted to the corresponding imidazoles in good to excellent yields via a rhodium(II)-catalyzed reaction with nitriles. Rhodium iminocarbenoids are proposed intermediates.

AB - Stable and readily available 1-sulfonyl triazoles are converted to the corresponding imidazoles in good to excellent yields via a rhodium(II)-catalyzed reaction with nitriles. Rhodium iminocarbenoids are proposed intermediates.

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U2 - 10.1021/ja805079v

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M3 - Article

C2 - 18855475

AN - SCOPUS:57349191194

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 45

ER -

Rhodium-catalyzed transannulation of 1,2,3-triazoles with nitriles

Abstract

ASJC Scopus subject areas

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