Abstract
The shifts induced in substrate nuclear resonances upon binding to a lanthanide ion or lanthanide complex result from a sum of the dipolar (pseudocontact) and scalar (contact) interactions. A dipolar shift results whenever the metal spin felt by a particular nucleus fails to average to zero while scalar shifts result from a delocalization of spin from the metal to the nucleus.
Original language | English (US) |
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Title of host publication | Unknown Host Publication Title |
Pages | 250-259 |
Number of pages | 10 |
Volume | 1 |
State | Published - 1976 |
ASJC Scopus subject areas
- Engineering(all)