Abstract
A spectrophotometric method for the simultaneous determination of Al(III), Co(II) and Ni(II) using Alizarin Red S as a chelating agent was developed. The parameters controlling the behavior of the system were investigated and optimum conditions were selected. The presence of non-linearities was checked using Mallows augmented partial residual plots. To take into account these non-linearities, a principal component analysis-adaptive neuro-fuzzy inference systems (PC-ANFISs) method was used for the analysis of ternary mixtures of Al(III), Co(II) and Ni(II) over the range of 0.05-0.90, 0.05-4.05 and 0.05-0.95 μg mL-1, respectively. Absorbance data were collected between 370 and 700 nm. The method was applied to accurately and simultaneously determines the content of metal ions in several synthetic mixtures.
Original language | English (US) |
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Pages (from-to) | 608-614 |
Number of pages | 7 |
Journal | Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy |
Volume | 73 |
Issue number | 4 |
DOIs | |
State | Published - Aug 15 2009 |
Keywords
- Alizarin Red S
- Aluminum
- Chemometrics
- Cobalt
- Nickel
- Spectrophotometry
ASJC Scopus subject areas
- Analytical Chemistry
- Atomic and Molecular Physics, and Optics
- Instrumentation
- Spectroscopy