Modified pyridinium chlorochromate oxidation of aldehydes to carbamoyl azides/acyl azides or carboxylic acids

P. S. Satyanarayana Reddy; Pendri Yadagiri; Sun Lumin; Dong Soo Shin; J R Falck

doi:10.1080/00397918808060749

Modified pyridinium chlorochromate oxidation of aldehydes to carbamoyl azides/acyl azides or carboxylic acids

P. S. Satyanarayana Reddy, Pendri Yadagiri, Sun Lumin, Dong Soo Shin, J R Falck

Biochemistry

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32 Scopus citations

Abstract

Aldehydes are transformed into carbamoyl azides/acyl azides by pyridinium chlorochromate in the presence of sodium azide. Comparable oxidations modified with sodium cyanide generate carboxylic acids from simple aliphatic aldehydes whereas conjugated aldehydes are unreactive.

Original language	English (US)
Pages (from-to)	545-551
Number of pages	7
Journal	Synthetic Communications
Volume	18
Issue number	5
DOIs	https://doi.org/10.1080/00397918808060749
State	Published - Apr 1 1988

ASJC Scopus subject areas

Organic Chemistry

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10.1080/00397918808060749

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title = "Modified pyridinium chlorochromate oxidation of aldehydes to carbamoyl azides/acyl azides or carboxylic acids",

abstract = "Aldehydes are transformed into carbamoyl azides/acyl azides by pyridinium chlorochromate in the presence of sodium azide. Comparable oxidations modified with sodium cyanide generate carboxylic acids from simple aliphatic aldehydes whereas conjugated aldehydes are unreactive.",

author = "{Satyanarayana Reddy}, {P. S.} and Pendri Yadagiri and Sun Lumin and Shin, {Dong Soo} and Falck, {J R}",

year = "1988",

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T1 - Modified pyridinium chlorochromate oxidation of aldehydes to carbamoyl azides/acyl azides or carboxylic acids

AU - Satyanarayana Reddy, P. S.

AU - Yadagiri, Pendri

AU - Lumin, Sun

AU - Shin, Dong Soo

AU - Falck, J R

PY - 1988/4/1

Y1 - 1988/4/1

N2 - Aldehydes are transformed into carbamoyl azides/acyl azides by pyridinium chlorochromate in the presence of sodium azide. Comparable oxidations modified with sodium cyanide generate carboxylic acids from simple aliphatic aldehydes whereas conjugated aldehydes are unreactive.

AB - Aldehydes are transformed into carbamoyl azides/acyl azides by pyridinium chlorochromate in the presence of sodium azide. Comparable oxidations modified with sodium cyanide generate carboxylic acids from simple aliphatic aldehydes whereas conjugated aldehydes are unreactive.

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DO - 10.1080/00397918808060749

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JO - Synthetic Communications

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Modified pyridinium chlorochromate oxidation of aldehydes to carbamoyl azides/acyl azides or carboxylic acids

Abstract

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