Abstract
Carbon-13 rotational-echo double-resonance (REDOR) NMR with 15N or 2H dephasing, combined with 15N REDOR NMR with 13C dephasing, has been obtained for a fully cross-linked epoxy resin prepared from a nominally uniform mixture of two parts of diglycidyl ether of Bisphenol A, one part of hexamethylenediamine, and 19% (by weight) antiplasticizer made from a carbonyl-13C-labeled aromatic acetamide. The antiplasiticizer contains the hydroxypropyl ether moiety of the epoxy repeat unit. A partially cross-linked resin was formed from five parts of epoxide, one part of hexamethylene-diamine, three parts of hexylamine, and 19% (by weight) antiplasticizer. Labels were introduced into the resin by replacing both methyl groups of the isopropylidene moiety of Bisphenol A with CD3 groups and by using [15N2]hexamethylenediamine and [15N]hexylamine (and their unlabeled counterparts) in various combinations. The antiplasticizer 13C-carbonyl carbon is 4.9 ± 0.5 Å from an amine 15N (with no preference for free or cross-linked sites) and 6.7 ± 1 Å from a quaternary carbon of the isopropylidene moiety.
Original language | English (US) |
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Pages (from-to) | 1214-1220 |
Number of pages | 7 |
Journal | Macromolecules |
Volume | 31 |
Issue number | 4 |
DOIs | |
State | Published - Feb 24 1998 |
ASJC Scopus subject areas
- Organic Chemistry
- Polymers and Plastics
- Inorganic Chemistry
- Materials Chemistry