Dual role of alkynyl halides in one-step synthesis of alkynyl epoxides

Alexander Trofimov; Natalia Chernyak; Vladimir Gevorgyan

doi:10.1021/ja806178r

Dual role of alkynyl halides in one-step synthesis of alkynyl epoxides

Alexander Trofimov, Natalia Chernyak, Vladimir Gevorgyan

Research output: Contribution to journal › Article › peer-review

58 Scopus citations

Abstract

It was demonstrated that alkynyl halides could serve as a source of Br⁺ and acetylide ions in the same transformation. This allowed for the efficient one-step preparation of alkynyl epoxides, important organic building blocks, from readily available starting materials.

Original language	English (US)
Pages (from-to)	13538-13539
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	130
Issue number	41
DOIs	https://doi.org/10.1021/ja806178r
State	Published - Oct 15 2008
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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title = "Dual role of alkynyl halides in one-step synthesis of alkynyl epoxides",

abstract = "It was demonstrated that alkynyl halides could serve as a source of Br+ and acetylide ions in the same transformation. This allowed for the efficient one-step preparation of alkynyl epoxides, important organic building blocks, from readily available starting materials.",

author = "Alexander Trofimov and Natalia Chernyak and Vladimir Gevorgyan",

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AU - Gevorgyan, Vladimir

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Y1 - 2008/10/15

N2 - It was demonstrated that alkynyl halides could serve as a source of Br+ and acetylide ions in the same transformation. This allowed for the efficient one-step preparation of alkynyl epoxides, important organic building blocks, from readily available starting materials.

AB - It was demonstrated that alkynyl halides could serve as a source of Br+ and acetylide ions in the same transformation. This allowed for the efficient one-step preparation of alkynyl epoxides, important organic building blocks, from readily available starting materials.

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Dual role of alkynyl halides in one-step synthesis of alkynyl epoxides

Abstract

ASJC Scopus subject areas

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