Distribution potential in small liquid-liquid systems

Vladislav S. Markin; Alexander G. Volkov

doi:10.1021/jp0485385

Distribution potential in small liquid-liquid systems

Vladislav S. Markin, Alexander G. Volkov

Neurology & Neurotherapeutics

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

For the first time, the distribution potential at the oil/water interface is calculated for a small system with a small volume of one of the phases. The analytical solution for a nanoheterogeneous system is obtained without assuming the electroneutrality in each phase. If the thickness of an oil droplet is comparable with the Debye screening length and the distribution potential exceeds kT/e ₀, then the solution can be found numerically.

Original language	English (US)
Pages (from-to)	13807-13812
Number of pages	6
Journal	Journal of Physical Chemistry B
Volume	108
Issue number	36
DOIs	https://doi.org/10.1021/jp0485385
State	Published - Sep 9 2004

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

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10.1021/jp0485385

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title = "Distribution potential in small liquid-liquid systems",

abstract = "For the first time, the distribution potential at the oil/water interface is calculated for a small system with a small volume of one of the phases. The analytical solution for a nanoheterogeneous system is obtained without assuming the electroneutrality in each phase. If the thickness of an oil droplet is comparable with the Debye screening length and the distribution potential exceeds kT/e 0, then the solution can be found numerically.",

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AB - For the first time, the distribution potential at the oil/water interface is calculated for a small system with a small volume of one of the phases. The analytical solution for a nanoheterogeneous system is obtained without assuming the electroneutrality in each phase. If the thickness of an oil droplet is comparable with the Debye screening length and the distribution potential exceeds kT/e 0, then the solution can be found numerically.

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JF - Journal of Physical Chemistry B

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ER -

Distribution potential in small liquid-liquid systems

Abstract

ASJC Scopus subject areas

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