Discrimination between magnesium(II) and calcium(II) by 1,4,7-tris(2-hydroxyalkyl)-1,4,7-triazacyclononane ligands

Jurriaan Huskens; A. Dean Sherry

doi:10.1039/a701107e

Discrimination between magnesium(II) and calcium(II) by 1,4,7-tris(2-hydroxyalkyl)-1,4,7-triazacyclononane ligands

Jurriaan Huskens, A. Dean Sherry

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The title ligands and their possible diastereomeric forms show large selectivity differences for complexation of Mg^II and Ca^II which are related to the twist angle of the plane of coordinating hydroxy groups relative to the plane of macrocyclic ring nitrogens.

Original language	English (US)
Pages (from-to)	845-846
Number of pages	2
Journal	Chemical Communications
Issue number	9
DOIs	https://doi.org/10.1039/a701107e
State	Published - 1997

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a701107e

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title = "Discrimination between magnesium(II) and calcium(II) by 1,4,7-tris(2-hydroxyalkyl)-1,4,7-triazacyclononane ligands",

abstract = "The title ligands and their possible diastereomeric forms show large selectivity differences for complexation of MgII and CaII which are related to the twist angle of the plane of coordinating hydroxy groups relative to the plane of macrocyclic ring nitrogens.",

author = "Jurriaan Huskens and Sherry, {A. Dean}",

year = "1997",

doi = "10.1039/a701107e",

language = "English (US)",

pages = "845--846",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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T1 - Discrimination between magnesium(II) and calcium(II) by 1,4,7-tris(2-hydroxyalkyl)-1,4,7-triazacyclononane ligands

AU - Huskens, Jurriaan

AU - Sherry, A. Dean

PY - 1997

Y1 - 1997

N2 - The title ligands and their possible diastereomeric forms show large selectivity differences for complexation of MgII and CaII which are related to the twist angle of the plane of coordinating hydroxy groups relative to the plane of macrocyclic ring nitrogens.

AB - The title ligands and their possible diastereomeric forms show large selectivity differences for complexation of MgII and CaII which are related to the twist angle of the plane of coordinating hydroxy groups relative to the plane of macrocyclic ring nitrogens.

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U2 - 10.1039/a701107e

DO - 10.1039/a701107e

M3 - Article

AN - SCOPUS:0002924460

SN - 1359-7345

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JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

Discrimination between magnesium(II) and calcium(II) by 1,4,7-tris(2-hydroxyalkyl)-1,4,7-triazacyclononane ligands

Abstract

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