TY - JOUR
T1 - Crystal and molecular structure of tetraethyl-ammonium bis (stilbene 1,2-dithiolato) nickelate(III)
AU - Rajalakshmi, A.
AU - Radha, Akella
AU - Seshasayee, M.
AU - Kuppusamy, P.
AU - Manoharan, P. T.
PY - 1989
Y1 - 1989
N2 - The crystals of the title compound are orthorhombic, space group Pca2l with the following parameters: a = 16.387(4), b = 7.507(2), c = 28.612(8) A°, V= 6343.8 A°3, Z = 4, Dx = 1.35 g cm-3, ℳ(MoK) = 0.753 mm-1, Final R = 0.11, Rw = 0.12 with 1.00/[σ2(Fo) + 0.0005 |F0|2] for 1073 unique redections [I> 3σ(I)]. The nickel atom has an approximate square planar configuration. The nitrogen atom of the cation exhibits a tetrahedral configuration. The anions are arranged along the a-axis at Z = 0.25 and 0.75 with the Nickel atoms nearly collinear.
AB - The crystals of the title compound are orthorhombic, space group Pca2l with the following parameters: a = 16.387(4), b = 7.507(2), c = 28.612(8) A°, V= 6343.8 A°3, Z = 4, Dx = 1.35 g cm-3, ℳ(MoK) = 0.753 mm-1, Final R = 0.11, Rw = 0.12 with 1.00/[σ2(Fo) + 0.0005 |F0|2] for 1073 unique redections [I> 3σ(I)]. The nickel atom has an approximate square planar configuration. The nitrogen atom of the cation exhibits a tetrahedral configuration. The anions are arranged along the a-axis at Z = 0.25 and 0.75 with the Nickel atoms nearly collinear.
KW - 2-dithiolene complex
KW - Crystal structure
KW - One-dimensional complex
KW - Stilbene 1
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U2 - 10.1524/zkri.1989.187.1-2.159
DO - 10.1524/zkri.1989.187.1-2.159
M3 - Article
AN - SCOPUS:84944301633
SN - 1433-7266
VL - 187
SP - 159
EP - 164
JO - Zeitschrift fur Kristallographie - New Crystal Structures
JF - Zeitschrift fur Kristallographie - New Crystal Structures
IS - 1-2
ER -