Crystal and molecular structure of tetraethyl-ammonium bis (stilbene 1,2-dithiolato) nickelate(III)

A. Rajalakshmi; Akella Radha; M. Seshasayee; P. Kuppusamy; P. T. Manoharan

doi:10.1524/zkri.1989.187.1-2.159

Crystal and molecular structure of tetraethyl-ammonium bis (stilbene 1,2-dithiolato) nickelate(III)

A. Rajalakshmi, Akella Radha, M. Seshasayee, P. Kuppusamy, P. T. Manoharan

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The crystals of the title compound are orthorhombic, space group Pca2_l with the following parameters: a = 16.387(4), b = 7.507(2), c = 28.612(8) A°, V= 6343.8 A°³, Z = 4, D_x = 1.35 g cm^-3, ℳ(MoK) = 0.753 mm^-1, Final R = 0.11, R_w = 0.12 with 1.00/[σ²(Fo) + 0.0005 |F₀|²] for 1073 unique redections [I> 3σ(I)]. The nickel atom has an approximate square planar configuration. The nitrogen atom of the cation exhibits a tetrahedral configuration. The anions are arranged along the a-axis at Z = 0.25 and 0.75 with the Nickel atoms nearly collinear.

Original language	English (US)
Pages (from-to)	159-164
Number of pages	6
Journal	Zeitschrift fur Kristallographie - New Crystal Structures
Volume	187
Issue number	1-2
DOIs	https://doi.org/10.1524/zkri.1989.187.1-2.159
State	Published - 1989

Keywords

2-dithiolene complex
Crystal structure
One-dimensional complex
Stilbene 1

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics
Inorganic Chemistry

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10.1524/zkri.1989.187.1-2.159

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title = "Crystal and molecular structure of tetraethyl-ammonium bis (stilbene 1,2-dithiolato) nickelate(III)",

abstract = "The crystals of the title compound are orthorhombic, space group Pca2l with the following parameters: a = 16.387(4), b = 7.507(2), c = 28.612(8) A°, V= 6343.8 A°3, Z = 4, Dx = 1.35 g cm-3, ℳ(MoK) = 0.753 mm-1, Final R = 0.11, Rw = 0.12 with 1.00/[σ2(Fo) + 0.0005 |F0|2] for 1073 unique redections [I> 3σ(I)]. The nickel atom has an approximate square planar configuration. The nitrogen atom of the cation exhibits a tetrahedral configuration. The anions are arranged along the a-axis at Z = 0.25 and 0.75 with the Nickel atoms nearly collinear.",

keywords = "2-dithiolene complex, Crystal structure, One-dimensional complex, Stilbene 1",

author = "A. Rajalakshmi and Akella Radha and M. Seshasayee and P. Kuppusamy and Manoharan, {P. T.}",

year = "1989",

doi = "10.1524/zkri.1989.187.1-2.159",

language = "English (US)",

volume = "187",

pages = "159--164",

journal = "Zeitschrift fur Kristallographie - New Crystal Structures",

issn = "1433-7266",

publisher = "R. Oldenbourg",

number = "1-2",

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TY - JOUR

T1 - Crystal and molecular structure of tetraethyl-ammonium bis (stilbene 1,2-dithiolato) nickelate(III)

AU - Rajalakshmi, A.

AU - Radha, Akella

AU - Seshasayee, M.

AU - Kuppusamy, P.

AU - Manoharan, P. T.

PY - 1989

Y1 - 1989

N2 - The crystals of the title compound are orthorhombic, space group Pca2l with the following parameters: a = 16.387(4), b = 7.507(2), c = 28.612(8) A°, V= 6343.8 A°3, Z = 4, Dx = 1.35 g cm-3, ℳ(MoK) = 0.753 mm-1, Final R = 0.11, Rw = 0.12 with 1.00/[σ2(Fo) + 0.0005 |F0|2] for 1073 unique redections [I> 3σ(I)]. The nickel atom has an approximate square planar configuration. The nitrogen atom of the cation exhibits a tetrahedral configuration. The anions are arranged along the a-axis at Z = 0.25 and 0.75 with the Nickel atoms nearly collinear.

AB - The crystals of the title compound are orthorhombic, space group Pca2l with the following parameters: a = 16.387(4), b = 7.507(2), c = 28.612(8) A°, V= 6343.8 A°3, Z = 4, Dx = 1.35 g cm-3, ℳ(MoK) = 0.753 mm-1, Final R = 0.11, Rw = 0.12 with 1.00/[σ2(Fo) + 0.0005 |F0|2] for 1073 unique redections [I> 3σ(I)]. The nickel atom has an approximate square planar configuration. The nitrogen atom of the cation exhibits a tetrahedral configuration. The anions are arranged along the a-axis at Z = 0.25 and 0.75 with the Nickel atoms nearly collinear.

KW - 2-dithiolene complex

KW - Crystal structure

KW - One-dimensional complex

KW - Stilbene 1

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U2 - 10.1524/zkri.1989.187.1-2.159

DO - 10.1524/zkri.1989.187.1-2.159

M3 - Article

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SN - 1433-7266

VL - 187

SP - 159

EP - 164

JO - Zeitschrift fur Kristallographie - New Crystal Structures

JF - Zeitschrift fur Kristallographie - New Crystal Structures

IS - 1-2

ER -

Crystal and molecular structure of tetraethyl-ammonium bis (stilbene 1,2-dithiolato) nickelate(III)

Abstract

Keywords

ASJC Scopus subject areas

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