Catalytic Enantioselective Hydrostannation of Cyclopropenes

Marina Rubina; Michael Rubin; Vladimir Gevorgyan

doi:10.1021/ja0496928

Catalytic Enantioselective Hydrostannation of Cyclopropenes

Marina Rubina, Michael Rubin, Vladimir Gevorgyan

Research output: Contribution to journal › Article › peer-review

85 Scopus citations

Abstract

The first examples of catalytic enantioselective hydrostannation of the C=C double bond of cyclopropenes has been demonstrated. This method allows for the efficient synthesis of 2,2-disubstituted cyclopropylstannanes with high degrees of diastereo- and enantioselectivity. The facial selectivity of this reaction is entirely controlled by steric factors. A variety of functional groups at C-3 of the cyclopropenes were tolerated.

Original language	English (US)
Pages (from-to)	3688-3689
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	126
Issue number	12
DOIs	https://doi.org/10.1021/ja0496928
State	Published - Mar 31 2004
Externally published	Yes

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja0496928

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abstract = "The first examples of catalytic enantioselective hydrostannation of the C=C double bond of cyclopropenes has been demonstrated. This method allows for the efficient synthesis of 2,2-disubstituted cyclopropylstannanes with high degrees of diastereo- and enantioselectivity. The facial selectivity of this reaction is entirely controlled by steric factors. A variety of functional groups at C-3 of the cyclopropenes were tolerated.",

author = "Marina Rubina and Michael Rubin and Vladimir Gevorgyan",

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AU - Gevorgyan, Vladimir

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AB - The first examples of catalytic enantioselective hydrostannation of the C=C double bond of cyclopropenes has been demonstrated. This method allows for the efficient synthesis of 2,2-disubstituted cyclopropylstannanes with high degrees of diastereo- and enantioselectivity. The facial selectivity of this reaction is entirely controlled by steric factors. A variety of functional groups at C-3 of the cyclopropenes were tolerated.

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Catalytic Enantioselective Hydrostannation of Cyclopropenes

Abstract

ASJC Scopus subject areas

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