Asymmetric synthesis of ageliferin

Xiao Wang; Zhiqiang Ma; Jianming Lu; Xianghui Tan; Chuo Chen

doi:10.1021/ja207386q

Asymmetric synthesis of ageliferin

Xiao Wang, Zhiqiang Ma, Jianming Lu, Xianghui Tan, Chuo Chen

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

We describe herein an asymmetric synthesis of ageliferin. A Mn(III)-mediated oxidative radical cyclization reaction was used as the key step to construct the core skeleton of this pyrrole-imidazole dimer. This approach resembles the biogenic [4 + 2] dimerization in an intramolecular fashion.

Original language	English (US)
Pages (from-to)	15350-15353
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	133
Issue number	39
DOIs	https://doi.org/10.1021/ja207386q
State	Published - Oct 5 2011

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja207386q

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title = "Asymmetric synthesis of ageliferin",

abstract = "We describe herein an asymmetric synthesis of ageliferin. A Mn(III)-mediated oxidative radical cyclization reaction was used as the key step to construct the core skeleton of this pyrrole-imidazole dimer. This approach resembles the biogenic [4 + 2] dimerization in an intramolecular fashion.",

author = "Xiao Wang and Zhiqiang Ma and Jianming Lu and Xianghui Tan and Chuo Chen",

year = "2011",

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AU - Wang, Xiao

AU - Ma, Zhiqiang

AU - Lu, Jianming

AU - Tan, Xianghui

AU - Chen, Chuo

PY - 2011/10/5

Y1 - 2011/10/5

N2 - We describe herein an asymmetric synthesis of ageliferin. A Mn(III)-mediated oxidative radical cyclization reaction was used as the key step to construct the core skeleton of this pyrrole-imidazole dimer. This approach resembles the biogenic [4 + 2] dimerization in an intramolecular fashion.

AB - We describe herein an asymmetric synthesis of ageliferin. A Mn(III)-mediated oxidative radical cyclization reaction was used as the key step to construct the core skeleton of this pyrrole-imidazole dimer. This approach resembles the biogenic [4 + 2] dimerization in an intramolecular fashion.

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AN - SCOPUS:80053302917

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SP - 15350

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JO - Journal of the American Chemical Society

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ER -

Asymmetric synthesis of ageliferin

Abstract

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