A mechanistic study of the anation of type 2 Cu(II) in fully oxidized lacease by azide and thiocyanate ions (X-) is reported. The rate data support a mechanism involving rapid formation of an outer-sphere complex (laccase-X-) followed by rate-limiting dissociative interchange to give the inner-sphere complex (laccase-X-) product.
|Original language||English (US)|
|Number of pages||5|
|State||Published - Aug 1982|
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