A silver-linked supramolecular cluster encapsulating a cesium cation

X. Sun; D. W. Johnson; K. N. Raymond; E. H. Wong

doi:10.1021/ic010154v

A silver-linked supramolecular cluster encapsulating a cesium cation

X. Sun, D. W. Johnson, K. N. Raymond, E. H. Wong

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Abstract

The solid-state, gas-phase, and solution characterization of the predesigned cluster Cs[(SnL₃)₂Ag₃] is presented (L = 4-(diphenylphosphino)benzene-1,2-diol). The solid-state structure confirms formation of a C_3h mesocate featuring three silver(I) cations linking two enantiomeric {SnL₃}^2- halves and encapsulating a Cs⁺ cation. The presence of the Cs⁺ cation is essential for successful formation of this pentametallic cluster. The ¹H, ¹³C, and ³¹P NMR spectra as well as FAB mass spectrum of the complex are consistent with retention of this supramolecular structure in solution and the gas phase.

Original language	English (US)
Pages (from-to)	4504-4506
Number of pages	3
Journal	Inorganic Chemistry
Volume	40
Issue number	17
DOIs	https://doi.org/10.1021/ic010154v
State	Published - Aug 13 2001

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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abstract = "The solid-state, gas-phase, and solution characterization of the predesigned cluster Cs[(SnL3)2Ag3] is presented (L = 4-(diphenylphosphino)benzene-1,2-diol). The solid-state structure confirms formation of a C3h mesocate featuring three silver(I) cations linking two enantiomeric {SnL3}2- halves and encapsulating a Cs+ cation. The presence of the Cs+ cation is essential for successful formation of this pentametallic cluster. The 1H, 13C, and 31P NMR spectra as well as FAB mass spectrum of the complex are consistent with retention of this supramolecular structure in solution and the gas phase.",

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year = "2001",

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T1 - A silver-linked supramolecular cluster encapsulating a cesium cation

AU - Sun, X.

AU - Johnson, D. W.

AU - Raymond, K. N.

AU - Wong, E. H.

PY - 2001/8/13

Y1 - 2001/8/13

N2 - The solid-state, gas-phase, and solution characterization of the predesigned cluster Cs[(SnL3)2Ag3] is presented (L = 4-(diphenylphosphino)benzene-1,2-diol). The solid-state structure confirms formation of a C3h mesocate featuring three silver(I) cations linking two enantiomeric {SnL3}2- halves and encapsulating a Cs+ cation. The presence of the Cs+ cation is essential for successful formation of this pentametallic cluster. The 1H, 13C, and 31P NMR spectra as well as FAB mass spectrum of the complex are consistent with retention of this supramolecular structure in solution and the gas phase.

AB - The solid-state, gas-phase, and solution characterization of the predesigned cluster Cs[(SnL3)2Ag3] is presented (L = 4-(diphenylphosphino)benzene-1,2-diol). The solid-state structure confirms formation of a C3h mesocate featuring three silver(I) cations linking two enantiomeric {SnL3}2- halves and encapsulating a Cs+ cation. The presence of the Cs+ cation is essential for successful formation of this pentametallic cluster. The 1H, 13C, and 31P NMR spectra as well as FAB mass spectrum of the complex are consistent with retention of this supramolecular structure in solution and the gas phase.

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JO - Inorganic Chemistry

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A silver-linked supramolecular cluster encapsulating a cesium cation

Abstract

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