TY - JOUR
T1 - A novel 1,2-migration of acyloxy, phosphatyloxy, and sulfonyloxy groups in allenes
T2 - Efficient synthesis of tri- and tetrasubstituted furans
AU - Sromek, Anna W.
AU - Kel'in, Alexander V.
AU - Gevorgyan, Vladimir
PY - 2004/4/19
Y1 - 2004/4/19
N2 - Heading south: The 1,2-migration of the acyloxy, phosphatyloxy, and sulfonyloxy groups in allenyl systems has been discovered. This migration, combined with the transition-metal-catalyzed cycloisomerization reaction, leads to the efficient synthesis of tri- and tetrasubstituted acyl-, phosphatyl-, and sulfonyloxy-substituted furans as single regioisomers.
AB - Heading south: The 1,2-migration of the acyloxy, phosphatyloxy, and sulfonyloxy groups in allenyl systems has been discovered. This migration, combined with the transition-metal-catalyzed cycloisomerization reaction, leads to the efficient synthesis of tri- and tetrasubstituted acyl-, phosphatyl-, and sulfonyloxy-substituted furans as single regioisomers.
KW - Cyclization
KW - Furans
KW - Homogeneous catalysis
KW - Rearrangement
KW - Synthetic methods
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U2 - 10.1002/anie.200353535
DO - 10.1002/anie.200353535
M3 - Article
C2 - 15108144
AN - SCOPUS:4544333104
SN - 1433-7851
VL - 43
SP - 2280
EP - 2282
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 17
ER -