@article{b113b2e20b9348c0a2ee0edac90b986d,
title = "A mechanistic study of the chromium(II)-mediated transformations of trichloromethyl alkyls and carbinols: evidence for carbene, carbyne, and carbenoid intermediates",
abstract = "Using CrCl2 in THF at room temperature, trichloromethyl carbinols and trichloromethylalkanes are readily transformed to the highly reactive α-chlorocarbenes, carbynes and α-chloro-α-chromium(III) vinylidene carbenoids. A mechanistic study is carried out to determine the nature of the intermediates.",
keywords = "Carbene, Carbyne, Chromium, Isotopic labeling, Rearrangement",
author = "Romain Bejot and Steve Tisserand and Li, {De Run} and Falck, {J R} and Charles Mioskowski",
note = "Funding Information: We are grateful to the Minist{\`e}re d{\'e}l{\'e}gu{\'e} {\`a} l{\textquoteright}Enseignement sup{\'e}rieur et {\`a} la Recherche, the CNRS, the Institut de Recherche Pierre Fabre, the Robert A. Welch Foundation and the NIH (GM31278, DK38226) for their financial support of this work. ",
year = "2007",
month = may,
day = "28",
doi = "10.1016/j.tetlet.2007.03.150",
language = "English (US)",
volume = "48",
pages = "3855--3858",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Limited",
number = "22",
}