A highly selective vanadium catalyst for benzylic C-H oxidation

Ji Bao Xia; Kevin W. Cormier; Chuo Chen

doi:10.1039/c2sc20178j

A highly selective vanadium catalyst for benzylic C-H oxidation

Ji Bao Xia, Kevin W. Cormier, Chuo Chen

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

Vanadium complexes have been used extensively to catalyze olefin and alcohol oxidation. However, their application in C-H oxidation has not been well-studied. We report herein that commercially available Cp ₂VCl₂ catalyzes benzylic C-H oxidation selectively and effectively, giving no aromatic oxidation products.

Original language	English (US)
Pages (from-to)	2240-2245
Number of pages	6
Journal	Chemical Science
Volume	3
Issue number	7
DOIs	https://doi.org/10.1039/c2sc20178j
State	Published - Jul 2012

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1039/c2sc20178j

Cite this

@article{7c85d65d1b6b44b5b90d805010b95e63,

title = "A highly selective vanadium catalyst for benzylic C-H oxidation",

abstract = "Vanadium complexes have been used extensively to catalyze olefin and alcohol oxidation. However, their application in C-H oxidation has not been well-studied. We report herein that commercially available Cp 2VCl2 catalyzes benzylic C-H oxidation selectively and effectively, giving no aromatic oxidation products.",

author = "Xia, {Ji Bao} and Cormier, {Kevin W.} and Chuo Chen",

year = "2012",

month = jul,

doi = "10.1039/c2sc20178j",

language = "English (US)",

volume = "3",

pages = "2240--2245",

journal = "Chemical Science",

issn = "2041-6520",

publisher = "Royal Society of Chemistry",

number = "7",

}

TY - JOUR

T1 - A highly selective vanadium catalyst for benzylic C-H oxidation

AU - Xia, Ji Bao

AU - Cormier, Kevin W.

AU - Chen, Chuo

PY - 2012/7

Y1 - 2012/7

N2 - Vanadium complexes have been used extensively to catalyze olefin and alcohol oxidation. However, their application in C-H oxidation has not been well-studied. We report herein that commercially available Cp 2VCl2 catalyzes benzylic C-H oxidation selectively and effectively, giving no aromatic oxidation products.

AB - Vanadium complexes have been used extensively to catalyze olefin and alcohol oxidation. However, their application in C-H oxidation has not been well-studied. We report herein that commercially available Cp 2VCl2 catalyzes benzylic C-H oxidation selectively and effectively, giving no aromatic oxidation products.

UR - http://www.scopus.com/inward/record.url?scp=84862168276&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84862168276&partnerID=8YFLogxK

U2 - 10.1039/c2sc20178j

DO - 10.1039/c2sc20178j

M3 - Article

AN - SCOPUS:84862168276

SN - 2041-6520

VL - 3

SP - 2240

EP - 2245

JO - Chemical Science

JF - Chemical Science

IS - 7

ER -

A highly selective vanadium catalyst for benzylic C-H oxidation

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this